Immobilization of a molecular cobalt electrocatalyst by hydrophobic interaction with a hematite photoanode for highly stable oxygen evolution.

نویسندگان

  • Khurram S Joya
  • Natalia Morlanés
  • Edward Maloney
  • Valentin Rodionov
  • Kazuhiro Takanabe
چکیده

A unique modification of a hematite photoanode with perfluorinated Co-phthalocyanine (CoFPc) by strong binding associated with hydrophobic interaction is demonstrated. The resultant molecular electrocatalyst - a hematite photoanode hybrid material showed a significant onset shift and high stability for the photoelectrochemical oxidation evolution reaction (OER).

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عنوان ژورنال:
  • Chemical communications

دوره 51 70  شماره 

صفحات  -

تاریخ انتشار 2015